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Solid oxide fuel cells that enable the detection of CO in reformed gases
- Source :
- Sensors and Actuators B: Chemical. 86:12-19
- Publication Year :
- 2002
- Publisher :
- Elsevier BV, 2002.
-
Abstract
- Solid oxide fuel cells (SOFCs) using Pd metal as the anode were fabricated for detection of CO in a flowing mixture of 0–4000 ppm CO, 50% H2, 10% CO2 and 6% H2O vapor between 300 and 400 °C. When 20 mol% Sm3+-doped CeO2 (SDC) was used as the electrolyte, the Pd anode was subjected to a large and reversible change in the anodic-reaction resistance with the CO concentration. This behavior brought about an almost linear relationship between the electromotive force (EMF) generated from the cell or the short-circuit current through the cell and the logarithm of the CO concentration. In both signals, the minimum detectable CO concentration was 50 ppm, and the 90% response and 90% recovery times were about 60 s. However, the EMF of the cell at a CO concentration of 0 ppm significantly deviated from the theoretical value, which made it difficult to obtain reproducible data. In addition, the current signal of a few μA at a CO concentration of 4000 ppm was not large enough to monitor the CO concentration exactly. The improvement of these problems could be achieved by using 25 mol% Y3+-doped BaCeO3 (BCY25) with higher ionic conduction as the electrolyte: the EMF of the cell at a CO concentration of 0 ppm was near the theoretical value; the current signal reached 66 μA at a CO concentration of 4000 ppm.
- Subjects :
- Electromotive force
Metals and Alloys
Analytical chemistry
Oxide
Electrolyte
Condensed Matter Physics
Signal
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Anode
Metal
chemistry.chemical_compound
chemistry
visual_art
Materials Chemistry
visual_art.visual_art_medium
Ionic conductivity
Electrical and Electronic Engineering
Current (fluid)
Instrumentation
Subjects
Details
- ISSN :
- 09254005
- Volume :
- 86
- Database :
- OpenAIRE
- Journal :
- Sensors and Actuators B: Chemical
- Accession number :
- edsair.doi...........f5cd0521103d484597f5ca822873e6d5