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Synthesis of arylcarboranechromium tricarbonyls

Authors :
A. S. Frenkel
Valery N. Kalinin
L. I. Zakharkin
G. K.-I. Magomedov
Source :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:875-877
Publication Year :
1977
Publisher :
Springer Science and Business Media LLC, 1977.

Abstract

1. The phenyl-, diphenyl-, benzyl-, and dibenzyl-o-carboranes, and the phenyl-, di-phenyl-, and dibenzyl-m-carboranes form arylcarboranechromium tricarbonyls when heated with Cr(CO)6. Dibenzyl-m-carborane reacts with Cr(CO)6 to give the mono- and binuclear complexes. 2. When heated, the arylcarboranes in arylcarboranechromium tricarbonyls are replaced by diphenyl and stilbene.

Details

ISSN :
15739171 and 05685230
Volume :
26
Database :
OpenAIRE
Journal :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :
edsair.doi...........f55706d17a29682f6aa4a0a5e4e796b9