Optical frequency standards based on mercury and aluminum ions

Single-trapped-ion frequency standards based on a 282 nm transition in 199 Hg + and on a 267 nm transition in 27 Al + have been developed at NIST over the past several years. Their frequencies are measured relative to each other and to the NIST primary frequency standard, the NIST-F1 cesium fountain, by means of a self-referenced femtosecond laser frequency comb. Both ion standards have demonstrated instabilities and inaccuracies of less than 1 × 10 −16 .