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(2,9-Dimethyl-1,10-phenanthroline-N1,N10)bis(O-ethyl dithiocarbonato-S,S')nickel(II)

Authors :
Y.-Q. Xue
Jing-Lin Zuo
Xiao-Ying Huang
Xiao-Zeng You
Ren-Gen Xiong
Y.-H. Guo
Source :
Acta Crystallographica Section C Crystal Structure Communications. 52:523-525
Publication Year :
1996
Publisher :
International Union of Crystallography (IUCr), 1996.

Abstract

The crystal structure of [Ni(C2H5OCS2)2(C14H12N2)] cis- [Ni(EtXA)2(2,9-dmphen)] (EtXA = ethyl xanthate, 2,9-dmphen = 2,9-dimethyl-1,10-phenanthroline), containing a distorted octahedral NiS4N2 core, is reported. The Ni—S bond lengths range from 2.376 (2) to 2.522 (2) A and the Ni—N bond lengths are 2.107 (4) and 2.153 (3) A, while the N(1)—Ni—N(2) chelate angle is 78.3 (1)°.

Details

ISSN :
01082701
Volume :
52
Database :
OpenAIRE
Journal :
Acta Crystallographica Section C Crystal Structure Communications
Accession number :
edsair.doi...........f51637076a32cb3e48ec03afa4694e2b