ChemInform Abstract: Stereodefined Construction of Trisubstituted Alkenes by Direct Coupling Reaction of Allylating Agents, Alkynes, and Organoboranes

Authors :: Masahiro Fukushima
Gen Onodera
Masanari Kimura
Hideaki Satomura
Daiki Takushima
Source :: ChemInform. 43
Publication Year :: 2012
Publisher :: Wiley, 2012.
Abstract: The palladium-catalyzed three-component coupling reaction of allylic alcohols, terminal alkynes, and organoboranes preferentially gives (E)-substituted alkylpentadienes, involving geminal allylation and alkylation at the acetylenic terminal carbon.

Subjects :: inorganic chemicals
Allylic rearrangement
Geminal
Chemistry
organic chemicals
food and beverages
chemistry.chemical_element
General Medicine
Alkylation
Medicinal chemistry
Coupling reaction
Pyrrole derivatives
Direct coupling
Carbon

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