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Synthesis and characterization of a novel cadmium(II) photoluminescent coordination polymer based on pyridine-2,3,5-tricarboxylic acid

Authors :
Jian-Guo Lin
Qing-Jin Meng
Ling Qiu
Source :
Journal of Molecular Structure. 980:257-260
Publication Year :
2010
Publisher :
Elsevier BV, 2010.

Abstract

Employing the multidentate ligand pyridine-2,3,5-tricarboxylic acid (H 3 PTC) as a bridge, a novel cadmium(II) coordination polymer [Cd 3 (PTC) 2 (bpy)(H 2 O) 4 ] ( 1 ) was obtained and characterized by single crystal X-ray diffraction. The PTC 3- ligand exhibits an interesting coordination mode to form a dense three-dimensional (3-D) framework of 1 . The complex displays good thermal stability and strong photoluminescence in the blue region band. Thus it may serve as a potential candidate of thermally stable blue-light-emitting luminescent material.

Details

ISSN :
00222860
Volume :
980
Database :
OpenAIRE
Journal :
Journal of Molecular Structure
Accession number :
edsair.doi...........f41d228e4687c5f1c9f387a87cd77ae6
Full Text :
https://doi.org/10.1016/j.molstruc.2010.07.028