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Synthesis and characterization of a novel cadmium(II) photoluminescent coordination polymer based on pyridine-2,3,5-tricarboxylic acid
- Source :
- Journal of Molecular Structure. 980:257-260
- Publication Year :
- 2010
- Publisher :
- Elsevier BV, 2010.
-
Abstract
- Employing the multidentate ligand pyridine-2,3,5-tricarboxylic acid (H 3 PTC) as a bridge, a novel cadmium(II) coordination polymer [Cd 3 (PTC) 2 (bpy)(H 2 O) 4 ] ( 1 ) was obtained and characterized by single crystal X-ray diffraction. The PTC 3- ligand exhibits an interesting coordination mode to form a dense three-dimensional (3-D) framework of 1 . The complex displays good thermal stability and strong photoluminescence in the blue region band. Thus it may serve as a potential candidate of thermally stable blue-light-emitting luminescent material.
- Subjects :
- chemistry.chemical_classification
Denticity
Photoluminescence
Ligand
Coordination polymer
Organic Chemistry
Inorganic chemistry
Tricarboxylic acid
Analytical Chemistry
Inorganic Chemistry
chemistry.chemical_compound
Crystallography
chemistry
Pyridine
Thermal stability
Single crystal
Spectroscopy
Subjects
Details
- ISSN :
- 00222860
- Volume :
- 980
- Database :
- OpenAIRE
- Journal :
- Journal of Molecular Structure
- Accession number :
- edsair.doi...........f41d228e4687c5f1c9f387a87cd77ae6
- Full Text :
- https://doi.org/10.1016/j.molstruc.2010.07.028