Tunable vicinal, geminal diphosphorylation and C–N bond phosphorylation of enaminones toward divergent phosphorylated ketone derivatives

The tunable reactions of enaminones with phosphine oxides/phosphonates in the form of vicinal- and geminal diphosphorylation, C–N bond phosphorylation have been developed, providing new methods for the synthesis of divergent phosphorylated molecules.