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Photocatalytic Degradation of Methyl Orange on Platinum and Palladium Co-doped TiO2 Nanoparticles

Authors :
Fa-Zhi Xie
Kan Zhang
Feng-Jun Zhang
Tao Chen
Tingyong Fang
Won-Chun Oh
Source :
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 42:685-691
Publication Year :
2012
Publisher :
Informa UK Limited, 2012.

Abstract

Pt and Pd co-doped TiO2 nanoparticles were synthesized using modified sol-gel processes and characterized by BET surface area, SEM, TEM, XRD, EDX, FT-IR, and UV-Vis spectroscopy. The results showed that the Pt/Pd-TiO2 nanoparticles possess high surface area and small particles size compared with individual Pt or Pd doped TiO2. The significantly high photocatalytic activity can be ascribed to the simultaneous effects of doped Pt and Pd by cascadal electron transfer from TiO2 to Pd to Pt and reach surface excitation state. And the optimum molar ratio of Pt/Pd at 1.5 can effectively reduce the electron–hole recombination rate.

Details

ISSN :
15533182 and 15533174
Volume :
42
Database :
OpenAIRE
Journal :
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Accession number :
edsair.doi...........f34f4128fab2ea4e72349d3e17bf3535