Back to Search
Start Over
Hydrothermal synthesis of copper complexes of 4′-pyridyl terpyridine: From discrete monomer to zigzag chain polymer
- Source :
- Inorganica Chimica Acta. 359:4027-4035
- Publication Year :
- 2006
- Publisher :
- Elsevier BV, 2006.
-
Abstract
- Seven copper complexes [Cu(L1)I2] (1), [Cu2(L1)2I2]2[Cu2(μ-I)2I2] (2), [Cu(L2)I2] (3), [Cu2(L2)(μ-I)I(PPh3)] (4), [Cu4(L2)2(μ-I)2I2] (5), {[Cu(L2)I]2[Cu2(μ-I)2I2]}n (6) and [Cu2(L2)(μ-I)2]n (7) have been prepared by reactions of ligands: 4′-(2-pyridyl)-2,2′:6′,2″-terpyridine (L1) and 4′-(3-pyridyl)-2,2′:6′,2″-terpyridine (L2) with CuI in hydrothermal conditions, respectively. By alternating the oxidations states of the metal centers, increasing stoichiometric metal/ligand ratio and introducing a second ligand, the compounds, were successfully developed from mononuclear (1 and 3) to multinuclear (2, 4 and 5) and polymers (6 and 7). The synthesis of these compounds may provide an approach for the construction of coordination compounds of 4′-pyridyl terpyridine with different nuclearity.
- Subjects :
- chemistry.chemical_classification
Ligand
Coordination polymer
Inorganic chemistry
chemistry.chemical_element
Copper
Coordination complex
Inorganic Chemistry
Metal
chemistry.chemical_compound
Crystallography
Monomer
chemistry
visual_art
Materials Chemistry
visual_art.visual_art_medium
Hydrothermal synthesis
Physical and Theoretical Chemistry
Terpyridine
Subjects
Details
- ISSN :
- 00201693
- Volume :
- 359
- Database :
- OpenAIRE
- Journal :
- Inorganica Chimica Acta
- Accession number :
- edsair.doi...........f1be4c4e5da25c2b45881d1ac0256f97