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Ultra-high quality factor and low dielectric constant of (Zn0.5Ti0.5)3+ co-substituted MgAl2O4 ceramic
- Source :
- Ceramics International. 47:22522-22529
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- In this study, MgAl2O4-based ceramics with high quality factor (Qf) and low dielectric constant (er ≤ 10) were obtained by fabricating MgAl2-x(Zn0.5Ti0.5)xO4 (x = 0–0.5) ceramics via conventional solid-state reaction method. Excellent microwave dielectric properties were achieved for samples at x = 0.5 and sintered at 1550 °C, i.e., er = 9.86, Qf = 263 900 GHz (five times better than that for x = 0 sample) and τf = −92 ppm/°C. The X-ray diffraction (XRD) patterns displayed characteristic peaks of MgAl2O4 with spinel structure. MgTi2O5 and MgTiO3 were considered as secondary phases. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and relative density analysis indicated that ultra-high Qf values were dominated by dense microstructure, secondary phase and cation vacancies; whereas er values were mainly affected by secondary phase and ionic polarizability. MgAl2-x(Zn0.5Ti0.5)xO4 ceramics with excellent microwave dielectric properties have potential application in millimeter-wave communication, dielectric filters, dielectric antennas and resonators.
- Subjects :
- 010302 applied physics
Materials science
Scanning electron microscope
Process Chemistry and Technology
Spinel
Analytical chemistry
Ionic bonding
02 engineering and technology
Dielectric
engineering.material
021001 nanoscience & nanotechnology
Microstructure
01 natural sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
visual_art
0103 physical sciences
Materials Chemistry
Ceramics and Composites
engineering
visual_art.visual_art_medium
Relative density
Ceramic
0210 nano-technology
Spectroscopy
Subjects
Details
- ISSN :
- 02728842
- Volume :
- 47
- Database :
- OpenAIRE
- Journal :
- Ceramics International
- Accession number :
- edsair.doi...........f1097fac54a5195169f760212294f6e7