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Layered nickel sulfide-reduced graphene oxide composites synthesized via microwave-assisted method as high performance anode materials of sodium-ion batteries

Authors :
Likun Pan
Ting Lu
Wei Qin
Daniel H. C. Chua
Taiqiang Chen
Source :
Journal of Power Sources. 302:202-209
Publication Year :
2016
Publisher :
Elsevier BV, 2016.

Abstract

Layered nickel sulfide (NS)-reduced graphene oxide (RGO) composites are prepared via a simple microwave-assisted method and subsequent annealing in N 2 /H 2 atmosphere. A detailed array of characterization tools are used to study their morphology, structure and electrochemical performance. It was found that these composites exhibit significantly improved sodium-ion storage ability as compared with pure NS under galvanostatic cycling at a specific current of 100 mA g −1 in a potential limitation of 0.005–3.0 V. Furthermore, the composite with the RGO content of 35 wt.% achieves a high maximum reversible specific capacity of about 391.6 mAh g −1 at a specific current of 100 mA g −1 after 50 cycles. These results prove that NS-RGO composites are highly promising when applied directly as anode materials in sodium-ion batteries.

Details

ISSN :
03787753
Volume :
302
Database :
OpenAIRE
Journal :
Journal of Power Sources
Accession number :
edsair.doi...........f0f8ec7cac4b5bee15b4a939a84ac282
Full Text :
https://doi.org/10.1016/j.jpowsour.2015.10.064