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Synthesis ofN-Alkoxy Aminesvia Catalytic Oxidation of Hydrocarbons

Authors :
Paul Adriaan Van Der Schaaf
Peter Nesvadba
Valérie Rast
Markus Frey
Andreas Hafner
Guenther Rist
Franz Schwarzenbach
Hans‐J. Kirner
Source :
Advanced Synthesis & Catalysis. 346:554-560
Publication Year :
2004
Publisher :
Wiley, 2004.

Abstract

Sterically hindered N-alkoxy amines 3 are synthesized in good yields by coupling nitroxides 2 with hydrocarbyl radicals generated in situ by t-BuOOH hydrogen abstraction from hydrocarbons. The reaction is catalyzed by copper halides as well as by onium iodides.

Details

ISSN :
16154169 and 16154150
Volume :
346
Database :
OpenAIRE
Journal :
Advanced Synthesis & Catalysis
Accession number :
edsair.doi...........f05dfc82346be16797bf8f6ea70f3748
Full Text :
https://doi.org/10.1002/adsc.200303194