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Synthesis ofN-Alkoxy Aminesvia Catalytic Oxidation of Hydrocarbons
- Source :
- Advanced Synthesis & Catalysis. 346:554-560
- Publication Year :
- 2004
- Publisher :
- Wiley, 2004.
-
Abstract
- Sterically hindered N-alkoxy amines 3 are synthesized in good yields by coupling nitroxides 2 with hydrocarbyl radicals generated in situ by t-BuOOH hydrogen abstraction from hydrocarbons. The reaction is catalyzed by copper halides as well as by onium iodides.
Details
- ISSN :
- 16154169 and 16154150
- Volume :
- 346
- Database :
- OpenAIRE
- Journal :
- Advanced Synthesis & Catalysis
- Accession number :
- edsair.doi...........f05dfc82346be16797bf8f6ea70f3748
- Full Text :
- https://doi.org/10.1002/adsc.200303194