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Synthesis of CETBz-TTF and CESBz-TTF: Preparation, structural and physical properties of their radical salts with paramagnetic Cu(II) complex anions
- Source :
- Synthetic Metals. 150:317-320
- Publication Year :
- 2005
- Publisher :
- Elsevier BV, 2005.
-
Abstract
- CETBz-TTF (4,5-bis(cyanoethylthio)benzo-tetrathiafulvalene) and CESBz-TTF (4,5-bis(cyanoethylseleno)benzo-tetrathiafulvalene) 5 have been synthesized from cyano precursor via a cross-coupling reaction. Radical salts with paramagnetic Cu(II) complex anions, such as (CETBz-TTF)2CuCl4 6 and (CESBz-TTF)2CuCl4 7 have been prepared. X-ray crystal structure and physical properties of these new compounds are presented.
- Subjects :
- Magnetic measurements
Single crystal growth
Stereochemistry
Chemistry
Mechanical Engineering
Metals and Alloys
Crystal structure
Condensed Matter Physics
Chemical synthesis
Electronic, Optical and Magnetic Materials
Bond length
Paramagnetism
Crystallography
Mechanics of Materials
X-ray crystallography
Materials Chemistry
Molecule
Subjects
Details
- ISSN :
- 03796779
- Volume :
- 150
- Database :
- OpenAIRE
- Journal :
- Synthetic Metals
- Accession number :
- edsair.doi...........eebfcf2ed88b0568770ec3fddf89e604
- Full Text :
- https://doi.org/10.1016/j.synthmet.2005.03.002