Particle Formation In A DC Discharge

We developed a model for the nucleation, growth and transport of carbonaceous dust particles in a non‐reactive gas dc discharge where the carbon source is provided by cathode sputtering. In a first part, we considered only the initial phase of the discharge when the dust charge density remains small with respect to the electron density. We found that an electric field reversal at the entrance of the negative glow region promotes trapping of negatively charged clusters and dust particles, confining them for long times in the plasma and favoring molecular growth. An essential ingredient for this process is electron attachment, which negatively charges the initially neutral clusters. We also showed that the field reversal mechanism can operate to trap negative clusters and particles under both electropositive and strongly electronegative plasma.