Structure and solution properties of radical-initiated poly(vinyl chloride). II. Correlation of solution properties

The results of detailed measurements of osmotic pressure, light scattering, and viscosity of poly(vinyl chloride) solutions are used to establish the molecular weight dependence of [η] and A2, to estimate the unperturbed dimensions of the poly(vinyl chloride) molecule, and to analyze critically the [η]–M correlations published hitherto.