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Trapping in situ scission products of C–O ester bonds by unique coordination supramolecular architectures
- Source :
- CrystEngComm. 11:1815
- Publication Year :
- 2009
- Publisher :
- Royal Society of Chemistry (RSC), 2009.
-
Abstract
- Various decomposition products of C–O ether bond cleavage have been trapped in supramolecular architectures as templates based on hydrothermal reaction of three-component metal–carboxylate–phen, which not only results in the formation of [5]pseudorotaxane structure, 3D porous framework and supramolecular structure, but also provides directly crystallographic evidence to explain how the C–O ether bond breaks during decomposition.
Details
- ISSN :
- 14668033
- Volume :
- 11
- Database :
- OpenAIRE
- Journal :
- CrystEngComm
- Accession number :
- edsair.doi...........ec61c8edc347713ee079d3a3f8544613