Back to Search Start Over

Hydroformylation of 1-hexene with rhodium in non-aqueous ionic liquids : how to design the solvent and the ligand to the reaction

Hydroformylation of 1-hexene with rhodium in non-aqueous ionic liquids : how to design the solvent and the ligand to the reaction

Authors :
Helene Olivier-Bourbigou
Lucien Saussine
Dominique Commereuc
Frederic Favre
Source :
Chemical Communications. :1360-1361
Publication Year :
2001
Publisher :
Royal Society of Chemistry (RSC), 2001.

Abstract

A wide range of ionic liquids based on imidazolium and pyrrolidinium cations and weakly coordinating anions proved to be efficient solvents for the biphasic rhodium catalyzed hydroformylation of 1-hexene; the reaction rate and regioselectivity, and the retention of the rhodium can be optimized by fitting the nature of the anions and cations of the ionic liquid and the modified phosphite or phosphine ligands.

Details

ISSN :
1364548X and 13597345
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi...........ec58c3d582c7e3454c43186b0ca46775
Full Text :
https://doi.org/10.1039/b104155j