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Hydroformylation of 1-hexene with rhodium in non-aqueous ionic liquids : how to design the solvent and the ligand to the reaction
Hydroformylation of 1-hexene with rhodium in non-aqueous ionic liquids : how to design the solvent and the ligand to the reaction
- Source :
- Chemical Communications. :1360-1361
- Publication Year :
- 2001
- Publisher :
- Royal Society of Chemistry (RSC), 2001.
-
Abstract
- A wide range of ionic liquids based on imidazolium and pyrrolidinium cations and weakly coordinating anions proved to be efficient solvents for the biphasic rhodium catalyzed hydroformylation of 1-hexene; the reaction rate and regioselectivity, and the retention of the rhodium can be optimized by fitting the nature of the anions and cations of the ionic liquid and the modified phosphite or phosphine ligands.
- Subjects :
- Ligand
Inorganic chemistry
Metals and Alloys
Regioselectivity
chemistry.chemical_element
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Rhodium
Solvent
1-Hexene
chemistry.chemical_compound
chemistry
Ionic liquid
Materials Chemistry
Ceramics and Composites
Hydroformylation
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi...........ec58c3d582c7e3454c43186b0ca46775
- Full Text :
- https://doi.org/10.1039/b104155j