Back to Search
Start Over
Niobium uptake by {P2W12} polyoxoanion with [NbO(C2O4)2(H2O)2]ā as Nb source
- Source :
- Inorganica Chimica Acta. 502:119319
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- Reaction of (NH4)[NbO(C2O4)2(H2O)2]·3H2O with K12[H2P2W12O48]ā24H2O in aqueous solution at pH 1.7 leads to the formation of mixed Nb/W species based on [(P2M18O60)2(µ-O)2]nā (M is a Nb/W mixture, when Nb ratio ranges from 6 to 8 and charge differs from 14- to 16- correspondingly) archetype. Direct crystallization from the reaction media results in colorless crystals with the composition formulated as K9(NH4)5[cis-(P2W15Nb3O61)2]·48H2O (1). Crystallization in the presence of (NMe2H2)Cl yields two phases (2a and 2b), containing the same [trans-(P2W14.7Nb3.3O61)2]14.6ā anions but different cation/H2O compositions. Both phases are present in a mixture with bulk composition corresponding to (NMe2H2)14.6[P2W14.7Nb3.3O61]2·28H2O (2). The solution behavior of 1 and 2 was studied with HR-ESI-MS and HPLC-ICP-AES. During XRPD study of 2 we found blue coloration of the thin film of the complex. This effect has only surface nature and was studied by diffuse reflectance spectra.
- Subjects :
- Aqueous solution
010405 organic chemistry
Niobium
chemistry.chemical_element
010402 general chemistry
01 natural sciences
0104 chemical sciences
law.invention
Inorganic Chemistry
Crystallography
Diffuse reflectance spectra
chemistry
law
Materials Chemistry
Physical and Theoretical Chemistry
Crystallization
Thin film
Powder diffraction
Natural bond orbital
Subjects
Details
- ISSN :
- 00201693
- Volume :
- 502
- Database :
- OpenAIRE
- Journal :
- Inorganica Chimica Acta
- Accession number :
- edsair.doi...........ec51b3a7d383dea59cab5dec2c01ce4e