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Catalytic processing of atmospheric residue of petroleum over AlSBA-15 nanomaterials with different acidity

Authors :
Regina C. O. B. Delgado
Cleyton K. D. Alberto
Kesia K. V. Castro
Antonio S. Araujo
Gabriel F. S. Barbosa
Ana C. F. Coriolano
Source :
Petroleum Science and Technology. 34:627-632
Publication Year :
2016
Publisher :
Informa UK Limited, 2016.

Abstract

The AlSBA-15 nanomaterials with different Si/Al ratios were investigated as a promising material for processing of atmospheric residue of petroleum (ATR). The processing was performed in a thermobalance using nitrogen as a carrier gas at different heating hates. The catalytic pyrolysis was performed with ATR sample containing 20% mass of AlSBA-15. Based on TG data by applying Ozawa-Flynn-Wall kinetic model, the activation energy for the pyrolysis of ATR was higher than for the ATR/AlSBA-15, throughout all range of decomposition, indicating that the nanostructured material is a promising material for processing petroleum residues in order to obtain liquid products in the gasoline and diesel range.

Details

ISSN :
15322459 and 10916466
Volume :
34
Database :
OpenAIRE
Journal :
Petroleum Science and Technology
Accession number :
edsair.doi...........eb8c46638a2abb15178fbd913bbf37b9