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Atomically Precise Alkynyl- and Halide-Protected AuAg Nanoclusters Au78Ag66(C≡CPh)48Cl8 and Au74Ag60(C≡CPh)40Br12: The Ligation Effects of Halides

Authors :
Guocheng Deng
Fengjiao Chen
Xiting Yuan
Boon K. Teo
Lan-Sun Zheng
Sami Malola
Nanfeng Zheng
Hannu Häkkinen
Source :
Inorganic Chemistry. 60:3529-3533
Publication Year :
2021
Publisher :
American Chemical Society (ACS), 2021.

Abstract

Reported herein are the synthesis and structures of two high-nuclearity AuAg nanoclusters, namely, [Au78Ag66(C≡CPh)48Cl8]q− and [Au74Ag60(C≡CPh)40Br12]2–. Both clusters possess a three-concentric-s...

Details

ISSN :
1520510X and 00201669
Volume :
60
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........eb873e5d26a56e22c0a59bfa8d609085