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Vibrational spectroscopy of SnBr4 and CCl4 using Lie algebraic approach

Authors :
Nirmal Kumar Sarkar
Ramendu Bhattacharjee
Joydeep Choudhury
Srinivasa Rao Karumuri
Source :
Pramana. 71:439-445
Publication Year :
2008
Publisher :
Springer Science and Business Media LLC, 2008.

Abstract

The stretching and bending vibrational energies of SnBr4 and CCl4 are calculated in the one-dimensional framework. The dynamical symmetry group of tetrahedral molecule was taken into consideration to construct the model Hamiltonian in this framework. Casimir and Majorana invariant operators were also determined accordingly. Using the model Hamiltonian so constructed, we reported the vibrational energy levels of SnBr4 and CCl4 molecules accurately.

Details

ISSN :
09737111 and 03044289
Volume :
71
Database :
OpenAIRE
Journal :
Pramana
Accession number :
edsair.doi...........eae8425bf68c4f904ea3c321ad924980