Siliciclastic-hosted zinc mineralization in the Proterozoic Vazante – Paracatu District, Brazil: Implications for metallogeny and sources of metals in sediment-hosted base metal systems

The Mesoproterozoic Upper Vazante Sequence is a mixed carbonate – siliciclastic marine succession, deposited between 1300 and 1100 Ma, which contains a variety of carbonate-hosted Zn silicate and Zn – Pb sulfide deposits in central Brazil. Carbonate-hosted Zn ± Pb mineralization is interpreted to have formed in two stages: one prior to the major deformation event and a second stage during the Brasiliano Orogeny (850 to 550 Ma). All known carbonate-hosted Zn-deposits and occurrences in the 250 km – long Vazante – Paracatu District are underlain by the Serra do Garrote Formation, a 500 + m-thick package made up mostly of phyllites and carbonaceous phyllites (>1% Total organic carbon) with minor interlayered meta-arenitic rocks. Our study revealed that siliciclastic rocks from the Serra do Garrote Formation contain horizons enriched in Zn (up to 0.46%). Siliciclastic-hosted zinc mineralization in the Serra do Garrote Formation is associated with pre-orogenic hydrothermal sulfide – quartz – chlorite layers and veinlets, which preferentially formed in carbonaceous and pyritic phyllites belonging to two subunits. The siliciclastic-hosted mineralization in these layers and veinlets is folded and crenulated (pre-orogenic). The geochemical signature of zinc-enrichment includes Cd, Cu, Hg, In, V ± Sb, Se, Mo, Re. Based on textural relationships and chemical U – Th – Total Pb dates of pre-orogenic and syn-orogenic monazite, sulfide mineralization in the Serra do Garrote Formation formed between 1200 and 650 Ma. Textural features indicate that base metals were locally remobilized within the Serra do Garrote Formation during the Brasiliano Orogeny, precipitating new generations of syn-orogenic sphalerite, chalcopyrite and pyrite. Mineralized zones in the Serra do Garrote Formation are distributed throughout the basin and have a similar geochemical signature as the overlying syn-orogenic carbonate-hosted base metal mineralization. However, there is no compelling evidence of depletion in the Serra do Garrote Formation, at the scale of this study, to suggest the ore-related metals have been leached from these siliciclastic rocks to be concentrated in the carbonate-hosted base metal deposits during the Brasiliano Orogeny. The findings of this study suggest that the Serra do Garrote Formation can be a potential target for siliciclastic-hosted base metal mineralization, similar to other Proterozoic sediment-hosted massive sulfide deposits.