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Effect of the adding ferrum in nickel/GDC anode-supported solid-oxide fuel cell in the intermediate temperature

Authors :
Yoshinobu Fujishiro
Koichi Hamamoto
Brian J. Ingram
Masanobu Awano
Bo Liang
Toshio Suzuki
John David Cater
Toshiaki Yamaguchi
Source :
International Journal of Hydrogen Energy. 36:10975-10980
Publication Year :
2011
Publisher :
Elsevier BV, 2011.

Abstract

NiO-Fe{sub 2}O{sub 3}/Gadolinium-doped CeO{sub 2} (GDC), NiO/GDC anode-supported fuel cells were compared at intermediate temperature to investigate the effect of ferrum (Fe) on anode microstructure and the cell performance. The porosity of Fe{sub 2}O{sub 3}-containing anode tubes are 36.3% (those sintered at 1350 C) and 31.8% (those sintered at 1400 C), which are respectively 1.1% and 5.9% higher than that of the tubes without Fe{sub 2}O{sub 3}. The effect of Fe on microstructure of anode has also been indicated by analyzing the volume fraction of the different-size pores. At the operating temperature of 600 C, the maximum power density increased nearly 100% using Fe-Ni (after reducing) bimetal anode. From the impedance spectra, it is deduced that the improvement in power density is due to the decrease of overpotential resistance (low frequency part) related to gas transportation.

Details

ISSN :
03603199
Volume :
36
Database :
OpenAIRE
Journal :
International Journal of Hydrogen Energy
Accession number :
edsair.doi...........e9f75455ad1c8ea37437bdd0b157c475
Full Text :
https://doi.org/10.1016/j.ijhydene.2011.05.142