An unusual 1D ladder-like silver(<scp>i</scp>) coordination polymer involving novel 1D → 3D five-folded interpenetrated and [3 + 2] catenaned features generated by Ag⋯O interactions

An unusual 1D ladder-like silver(I) complex has been synthesized and characterized. The polymer exhibits interesting plywood-like stacking arrays and a novel five-folded interpenetrated supramolecular network with [3 + 2] catenations.