ChemInform Abstract: Palladium-Catalyzed Cross-Coupling Reactions of Organogold(I) Phosphanes with Allylic Electrophiles

Authors :: Miguel Peña-López
Luis A. Sarandeses
José Pérez Sestelo
Miguel Ayan‐Varela
Source :: ChemInform. 43
Publication Year :: 2012
Publisher :: Wiley, 2012.
Abstract: The title reaction of aryl- or alkenylgold phosphane complexes (II) with allylic chlorides, bromides or acetates proceeds with high regioselectivity (γ-products are not detected).

Subjects :: Allylic rearrangement
Chemistry
organic chemicals
Aryl
food and beverages
Regioselectivity
chemistry.chemical_element
General Medicine
Medicinal chemistry
Coupling reaction
Catalysis
chemistry.chemical_compound
Electrophile
Palladium

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