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ChemInform Abstract: Superbasic Bridgehead Diphosphines: The Effects of Strain and Intrabridgehead P×××P Bonding on Phosphine Basicity
- Source :
- ChemInform. 32
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- The basicity order in acetonitrile for a series of phosphines is: 1,5-diphosphabicyclo[3.3.3]undecane 1 (pKa for the protonated ion ∼ 17.9)
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 32
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........e81ec2b8041faa3257230061c5a1cf3e
- Full Text :
- https://doi.org/10.1002/chin.200121018