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Synthesis and Characterization of UV Crosslinkable and Highly Sulfonated Block Copolymer by Living Radical Polymerization

Authors :
Kyung Youl Baek
Source :
Molecular Crystals and Liquid Crystals. 520:256/[532]-261/[537]
Publication Year :
2010
Publisher :
Informa UK Limited, 2010.

Abstract

UV crosslinkable sulfonated block copolymers of neopentyl p-styrene sulfonate (NSS) and 2-cinnamoylethyl acrylate (CEA) were synthesized by living radical polymerization. For this, the block copolymers of 2-(trimethylsilyl)ethyl acrylate (TMSEA) and NSS were first synthesized by sequential CuBr catalyzed living radical polymerization with 2-bromopropionate (EBP) initiator and N,N,N′,N′-pentamethylethyleneamine (PMDETA) ligand. Obtained well defined block copolymers (polydispersity

Details

ISSN :
15635287 and 15421406
Volume :
520
Database :
OpenAIRE
Journal :
Molecular Crystals and Liquid Crystals
Accession number :
edsair.doi...........e7e8d2850ebcfc3a3a261ba4f1a8018d
Full Text :
https://doi.org/10.1080/15421400903584580