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Synthesis and Characterization of UV Crosslinkable and Highly Sulfonated Block Copolymer by Living Radical Polymerization
- Source :
- Molecular Crystals and Liquid Crystals. 520:256/[532]-261/[537]
- Publication Year :
- 2010
- Publisher :
- Informa UK Limited, 2010.
-
Abstract
- UV crosslinkable sulfonated block copolymers of neopentyl p-styrene sulfonate (NSS) and 2-cinnamoylethyl acrylate (CEA) were synthesized by living radical polymerization. For this, the block copolymers of 2-(trimethylsilyl)ethyl acrylate (TMSEA) and NSS were first synthesized by sequential CuBr catalyzed living radical polymerization with 2-bromopropionate (EBP) initiator and N,N,N′,N′-pentamethylethyleneamine (PMDETA) ligand. Obtained well defined block copolymers (polydispersity
Details
- ISSN :
- 15635287 and 15421406
- Volume :
- 520
- Database :
- OpenAIRE
- Journal :
- Molecular Crystals and Liquid Crystals
- Accession number :
- edsair.doi...........e7e8d2850ebcfc3a3a261ba4f1a8018d
- Full Text :
- https://doi.org/10.1080/15421400903584580