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Triazole linked ruthenium(<scp>ii</scp>)–porphyrin: influence of the connectivity pattern on photophysical and electrochemical properties
- Source :
- New Journal of Chemistry. 40:8878-8885
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- Herein a copper catalysed click reaction has been used to covalently link π-conjugated 1,2,3-triazolyl zinc(II) porphyrin and ruthenium(II) bipyridyl with a single change in their connection through the linker. The properties of these compounds have been compared with the porphyrin–ruthenium(II) tris(bipyridine) and ruthenium(II) trisbipyridine complexes. Extensive photophysical and electrochemical studies reveal that changes in the electronic properties of the conjugates are a consequence of the different connectivity patterns with regular and inverse triazolyl–pyridyl moieties.
- Subjects :
- 010405 organic chemistry
Triazole
chemistry.chemical_element
General Chemistry
010402 general chemistry
Photochemistry
Electrochemistry
01 natural sciences
Porphyrin
Catalysis
0104 chemical sciences
Ruthenium
chemistry.chemical_compound
Bipyridine
chemistry
Covalent bond
Polymer chemistry
Materials Chemistry
Click chemistry
Linker
Subjects
Details
- ISSN :
- 13699261 and 11440546
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- New Journal of Chemistry
- Accession number :
- edsair.doi...........e770e25f48863710a9034270d11fd37c