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An electrochemical off–on method for pyrimidin-2(1H)-one synthesis via three-component cyclization
- Source :
- Green Chemistry. 21:4495-4498
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry (RSC), 2019.
-
Abstract
- A green and simple ‘one-pot’ electrochemical off–on approach to synthesize pyrimidin-2(1H)-ones was realized without any catalyst, oxidant and toxic reagent. The desired products were obtained in moderate to good yields after the stepwise ‘one-pot’ reaction. The results of control experiments and cyclic voltammetry indicated that the electrooxidation of DHPMs might proceed via two steps process losing two-electrons and two-protons by absorption control with radical intermediates.
Details
- ISSN :
- 14639270 and 14639262
- Volume :
- 21
- Database :
- OpenAIRE
- Journal :
- Green Chemistry
- Accession number :
- edsair.doi...........e75dd0961b943757542adc4902561e4e