Mechanistic Insights into CO2 Methanation over Ru-Substituted CeO2

CO2 methanation is an important probe reaction to understand CO2 interactions with catalytic surfaces. The importance of this reaction is further increased by its association with CO2 utilization. This study reports the mechanistic aspects of CO2 methanation over combustion synthesized Ru-substituted CeO2 catalyst. Temperature-programmed reaction experiments were carried out to understand the interaction of CO2, H2, and their stoichiometric mixture with the catalyst surface. In situ FTIR spectroscopy was used to identify the intermediates of the reaction. It was observed that CO2 adsorption took place on the surface of Ce0.95Ru0.05O2 and the formation of surface carbonate intermediates took place only when H2 was present in the gas phase. In the absence of H2, CO2 did not show any indication for chemisorption. This behavior was explained in terms of the reaction between CO2 and the surface hydroxyls leading to the formation of a vacancy. Upon dissociation, carbonates led to chemisorbed CO which eventually...