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A novel two-dimensional structure containing the first antimony-substituted polyoxovandium clusters: [{Co(en)2}2SbIII8VIV14O42(H2O)]·6H2O
- Source :
- J. Chem. Soc., Dalton Trans.. :3275-3276
- Publication Year :
- 2002
- Publisher :
- Royal Society of Chemistry (RSC), 2002.
-
Abstract
- The novel framework [{Co(en)2}2SbIII8VIV14O42(H2O)]·6H2O is composed of two-dimensional arrays of {SbIII8VIV14O42(H2O)} clusters interlinked via {Co(en)2} bridging groups; such antimony–vanadium clusters with antimony and vanadium in low oxidation states were previously unknown.
Details
- ISSN :
- 13645447 and 14727773
- Database :
- OpenAIRE
- Journal :
- J. Chem. Soc., Dalton Trans.
- Accession number :
- edsair.doi...........e50d7fce2aaf37eac2d8300371410e97
- Full Text :
- https://doi.org/10.1039/b206250j