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μ-Aqua-bis(μ-4-chlorobenzoato)bis[(4-chlorobenzoato)(1,10-phenanthroline)manganese(II)]

Authors :
Wen-Dong Song
Sheng-Li Sun
Yu-Li Shen
Source :
Acta Crystallographica Section E Structure Reports Online. 63:m1309-m1311
Publication Year :
2007
Publisher :
International Union of Crystallography (IUCr), 2007.

Abstract

The title complex mol­ecule, [Mn2(C7H4ClO2)4(C12H8N2)2(H2O)], possesses crystallographically imposed C2 symmetry. Each MnII atom is coordinated by three carboxyl O atoms from three 4-chloro­benzoate ligands, two N atoms from one 1,10-phenanthroline ligand and one bridging water mol­ecule in a distorted octa­hedral coordination geometry. The Mn⋯Mn separation is 3.512 (3) A. Symmetrically related dinuclear mol­ecules form chains parallel to the c axis via π–π stacking inter­actions.

Details

ISSN :
16005368
Volume :
63
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........e4dba1c32f5672f6d92264de660db49e
Full Text :
https://doi.org/10.1107/s1600536807017801