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Alternative synthetic approaches to (±)-euryfuran via the furan ring transfer reaction

Authors :
Seizo Soejima
Yoskiyasu Baba
Ken Kanematsu
Toshihiro Sakamoto
Source :
Tetrahedron. 50:5645-5658
Publication Year :
1994
Publisher :
Elsevier BV, 1994.

Abstract

Two effective synthetic approaches to (±)-euryfuran 1 are described. One synthetic route makes use of sequential furan ring transfer reaction type I and type III as key steps followed by Eschenmoser-type [3,3]sigmatropic rearrangement, and another route proceeded through furan ring transfer reaction type I and annulation with ethyl vinyl ketone subsequently.

Details

ISSN :
00404020
Volume :
50
Database :
OpenAIRE
Journal :
Tetrahedron
Accession number :
edsair.doi...........e3704d5406ae998265260fbfcb01864e