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The reaction of trichlorosilane with hydrocarbons at high temperatures

Authors :
N. G. Maksimova
Vladimir F. Mironov
Source :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 11:1223-1225
Publication Year :
1962
Publisher :
Springer Science and Business Media LLC, 1962.

Abstract

1. A new reaction of trichlorosilane with saturated hydrocarbons has been found which takes place at about 600° in a circulating system and results in the formation of organic compounds of silicon of the type RSiCl3 with a yield of more than 60%. 2. Regardless of the nature of the hydrocarbon, methyltrichlorosilane and vinyltrichlorosilane are always found among the silico-organic compounds that are formed; their yield is as much as about 30% in some cases.

Details

ISSN :
15739171 and 05685230
Volume :
11
Database :
OpenAIRE
Journal :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :
edsair.doi...........e315311f4980a68bca4b2a02c7c70ac8