The Direct Measurement of Carbon in Wells Containing Oil and Natural Gas Using a Pulsed Neutron Mineralogy Tool

The assessment of reservoir productivity and subsurface hydrocarbon can be significantly enhanced through an understanding of formation mineralogy and organic carbon. Such information allows petrophysicists to resolve ambiguities in their predictions of reservoir hydrocarbon potential. While core samples are a prime source for exact formation mineralogy, excellent results can also be derived in a timely and cost-efficient manner from in-situ log chemistry measurements of the rock. A direct measurement of the formation's elemental concentrations is achieved using a gamma ray scintillation sensor in combination with a 14-MeV pulsed-neutron generator. The most important element measured is carbon, as it may provide a direct indication of reservoir hydrocarbons. This paper presents a method for determining the amount of organic carbon in subsurface formations using a pulsed-neutron mineralogy tool and a natural gamma ray spectroscopy tool. The natural, inelastic, and capture gamma ray energy spectra from these instruments are used to extract the chemistry of the subsurface formation being investigated. The elemental concentrations measured include Al, C, Ca, Fe, Gd, K, Mg, S, Si, Th, Ti, and U. Carbon is very difficult to measure without the inelastic spectrum generated from a pulsed-neutron source. An interpretation process, based upon the geochemistry of petroleum-bearing formations, is employed to derive the lithology and mineralogy which leads to the interpretation of the carbon measurement. The oil saturation can be computed in conventional reservoirs, assuming that the amount of carbon in excess of that required for the inorganic matrix mineralogy is part of the pore fluid as hydrocarbon. The direct carbon measurement is also important in laminated shaly sands or in low-salinity reservoirs, where oil saturation determination from indirect measurements, such as resistivity, is not compatible with the environment. In other formations the carbon can be determined to be a component of the rock matrix as kerogen or coal, both of which are uniquely identified with this logging system. Kerogen becomes extremely important in the evaluation of shale gas formations. Field examples are presented to illustrate the effectiveness of the carbon measurement.