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Triphenylamine-based hole transporting materials with thiophene-derived bridges for perovskite solar cells
- Source :
- Synthetic Metals. 261:116323
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- A triphenylamine-based compound containing benzoyl[1,2-b:4,5-b’]dithiophene (BDT) derivative (BTPA-2) has been synthesized and employed in FA0.85MA0.15PbI3 perovskite solar cells (PSCs) as the hole transporting material (HTM). The reference BTPA-1 containing thiophene bridge was also prepared for a comparative study. Compared to the thiophene unit in BTPA-1, the hexyloxy substituted BDT unit in BTPA-2 made the HOMO energy level lower. The more conjugated system with the BDT unit can improve the conductivity and hole mobility. The BTPA-1 and BTPA-2 based FA0.85MA0.15PbI3 PSCs showed the best power conversion efficiencies (PCE) of 12.76 % and 13.97 %, respectively. Larger Voc and higher Jsc for the BTPA-2 based PSC were attributed to its reduced interfacial recombination and more conjugated system compared to the BTPA-1 based PSCs. More hydrophobic property of BTAP-2 made its PSC exhibit better environmental stability than BTPA-1.
- Subjects :
- Electron mobility
Materials science
Mechanical Engineering
Metals and Alloys
02 engineering and technology
Conductivity
Conjugated system
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
Photochemistry
Triphenylamine
01 natural sciences
0104 chemical sciences
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
chemistry
Mechanics of Materials
Materials Chemistry
Thiophene
Environmental stability
0210 nano-technology
Derivative (chemistry)
Perovskite (structure)
Subjects
Details
- ISSN :
- 03796779
- Volume :
- 261
- Database :
- OpenAIRE
- Journal :
- Synthetic Metals
- Accession number :
- edsair.doi...........e115c33044ed08f7de690246fa3b6169