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Kitaev interactions in the Co honeycomb antiferromagnets Na3Co2SbO6 and Na2Co2TeO6
- Source :
- Physical Review B. 102
- Publication Year :
- 2020
- Publisher :
- American Physical Society (APS), 2020.
-
Abstract
- ${\mathrm{Co}}^{2+}$ ions in an octahedral crystal field stabilize a ${j}_{\mathrm{eff}}=1/2$ ground state with an orbital degree of freedom and have been recently put forward for realizing Kitaev interactions, a prediction we have tested by investigating spin dynamics in two cobalt honeycomb lattice compounds, ${\mathrm{Na}}_{2}{\mathrm{Co}}_{2}{\mathrm{TeO}}_{6}$ and ${\mathrm{Na}}_{3}{\mathrm{Co}}_{2}{\mathrm{SbO}}_{6}$, using inelastic neutron scattering. We used linear spin wave theory to show that the magnetic spectra can be reproduced with a spin Hamiltonian including a dominant Kitaev nearest-neighbor interaction, weaker Heisenberg interactions up to the third neighbor, and bond-dependent off-diagonal exchange interactions. Beyond the Kitaev interaction that alone would induce a quantum spin liquid state, the presence of these additional couplings is responsible for the zigzag-type long-range magnetic ordering observed at low temperature in both compounds. These results provide evidence for the realization of Kitaev-type coupling in cobalt-based materials, despite hosting a weaker spin-orbit coupling than their $4d$ and $5d$ counterparts.
- Subjects :
- Physics
Condensed matter physics
02 engineering and technology
021001 nanoscience & nanotechnology
01 natural sciences
7. Clean energy
Inelastic neutron scattering
Spectral line
3. Good health
Ion
Octahedron
Spin wave
Lattice (order)
0103 physical sciences
Condensed Matter::Strongly Correlated Electrons
Quantum spin liquid
010306 general physics
0210 nano-technology
Ground state
Subjects
Details
- ISSN :
- 24699969 and 24699950
- Volume :
- 102
- Database :
- OpenAIRE
- Journal :
- Physical Review B
- Accession number :
- edsair.doi...........df012fd80cd4b663ca3e42f65a7c2ded
- Full Text :
- https://doi.org/10.1103/physrevb.102.224429