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Kitaev interactions in the Co honeycomb antiferromagnets Na3Co2SbO6 and Na2Co2TeO6

Authors :
Abdellali Hadj-Azzem
Jose A. Rodriguez-Rivera
S. Petit
V. Balédent
Chris Stock
Françoise Damay
M. Songvilay
P. Lejay
J. Robert
M. Jiménez-Ruiz
E. Pachoud
William Ratcliff
Virginie Simonet
Source :
Physical Review B. 102
Publication Year :
2020
Publisher :
American Physical Society (APS), 2020.

Abstract

${\mathrm{Co}}^{2+}$ ions in an octahedral crystal field stabilize a ${j}_{\mathrm{eff}}=1/2$ ground state with an orbital degree of freedom and have been recently put forward for realizing Kitaev interactions, a prediction we have tested by investigating spin dynamics in two cobalt honeycomb lattice compounds, ${\mathrm{Na}}_{2}{\mathrm{Co}}_{2}{\mathrm{TeO}}_{6}$ and ${\mathrm{Na}}_{3}{\mathrm{Co}}_{2}{\mathrm{SbO}}_{6}$, using inelastic neutron scattering. We used linear spin wave theory to show that the magnetic spectra can be reproduced with a spin Hamiltonian including a dominant Kitaev nearest-neighbor interaction, weaker Heisenberg interactions up to the third neighbor, and bond-dependent off-diagonal exchange interactions. Beyond the Kitaev interaction that alone would induce a quantum spin liquid state, the presence of these additional couplings is responsible for the zigzag-type long-range magnetic ordering observed at low temperature in both compounds. These results provide evidence for the realization of Kitaev-type coupling in cobalt-based materials, despite hosting a weaker spin-orbit coupling than their $4d$ and $5d$ counterparts.

Details

ISSN :
24699969 and 24699950
Volume :
102
Database :
OpenAIRE
Journal :
Physical Review B
Accession number :
edsair.doi...........df012fd80cd4b663ca3e42f65a7c2ded
Full Text :
https://doi.org/10.1103/physrevb.102.224429