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ChemInform Abstract: A Formal Synthesis of (.+-.) Lycoramine via an Intramolecular Heck Reaction

Authors :
Catherine Guillou
Emmanuel Gras
Claude Thal
Source :
ChemInform. 31
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

The first use of an intramolecular Heck reaction for the construction of the quaternary centre of a galanthamine-like Amaryllidaceae alkaloid is described. The use of the acetate anion is shown as an activating factor in the 6- exo cyclisation of 5 .

Details

ISSN :
15222667 and 09317597
Volume :
31
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........defe972c53c034bd211e586a7f6235cb