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Na2.4Al0.4Mn2.6O7 anionic redox cathode material for sodium-ion batteries – a combined experimental and theoretical approach to elucidate its charge storage mechanism

Authors :
Cindy Soares
Begoña Silván
Yong-Seok Choi
Veronica Celorrio
Valerie R. Seymour
Giannantonio Cibin
John M. Griffin
David O. Scanlon
Nuria Tapia-Ruiz
Source :
Journal of Materials Chemistry A. 10:7341-7356
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

Al substitution and subsequent Na excess in Na2Mn3O7 were achieved by a ceramic method, realizing the high-performance Na2.4Al0.4Mn2.6O7 oxygen-redox cathode for Na-ion batteries. A comparison between the two cathodes revealed the role of Al doping.

Details

ISSN :
20507496 and 20507488
Volume :
10
Database :
OpenAIRE
Journal :
Journal of Materials Chemistry A
Accession number :
edsair.doi...........dedb9641556cc2218c42fa798ceb1dc0