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Mesoporous Polymeric Support Retaining High Catalytic Activity of Polyoxotungstate for Liquid-Phase Olefin Epoxidation using H2O2
- Source :
- ChemCatChem. 3:1435-1438
- Publication Year :
- 2011
- Publisher :
- Wiley, 2011.
-
Abstract
- However, polymer resin basedporous supports typically have a wide distribution of pore di-ameters, ranging from micropores ( 50 nm). A large portion of the catalytic groups can be sup-ported within micropores under these circumstances, leadingto serious diffusion limitations. Another problem is that theloosely cross-linked polymeric frameworks can easily swell inmany organic solvents. This swelling can lead to the closing ofpore mouths under reaction conditions with organic solvents.In addition, water (H
Details
- ISSN :
- 18673880
- Volume :
- 3
- Database :
- OpenAIRE
- Journal :
- ChemCatChem
- Accession number :
- edsair.doi...........de2cb6412f16ae0b1116372aeb264f5b