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Mesoporous Polymeric Support Retaining High Catalytic Activity of Polyoxotungstate for Liquid-Phase Olefin Epoxidation using H2O2

Authors :
Sanjeev P. Maradur
Kyeongyeon Kim
Dae-Heung Choi
Ryong Ryoo
Changbum Jo
Source :
ChemCatChem. 3:1435-1438
Publication Year :
2011
Publisher :
Wiley, 2011.

Abstract

However, polymer resin basedporous supports typically have a wide distribution of pore di-ameters, ranging from micropores ( 50 nm). A large portion of the catalytic groups can be sup-ported within micropores under these circumstances, leadingto serious diffusion limitations. Another problem is that theloosely cross-linked polymeric frameworks can easily swell inmany organic solvents. This swelling can lead to the closing ofpore mouths under reaction conditions with organic solvents.In addition, water (H

Details

ISSN :
18673880
Volume :
3
Database :
OpenAIRE
Journal :
ChemCatChem
Accession number :
edsair.doi...........de2cb6412f16ae0b1116372aeb264f5b