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Inhibition of Copper Corrosion in Binary Acid Mixtures (HNO3 + H3PO4) using Tamarix Boveana Plant Extract
- Source :
- Protection of Metals and Physical Chemistry of Surfaces. 55:1173-1181
- Publication Year :
- 2019
- Publisher :
- Pleiades Publishing Ltd, 2019.
-
Abstract
- In this study, the inhibition effect of Tamarix Boveana (TB) extract on Cu corrosion in 1 mol L–1 (HNO3 + H3PO4) mixture was studied. Electrochemical techniques such as (potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM)) and non-electrochemical technique such as mass loss were used. Results showed that TB extract has good inhibition efficiency (IE), follows Langmuir adsorption isotherm and all of the methods are in good agreement. The IE increased by increasing the concentration of the extract and decreased by increasing the temperature so, the extract adsorbed on Cu surface physically. The IE depends on the concentration of the extract and reaches 73.5% at 300 ppm of the extract. PP results revealed that the (TB) extract doings as mixed type one. Surface analysis revealed that the extract components are adsorbed on Cu surface forming a film.
- Subjects :
- Tamarix boveana
Chemistry
020209 energy
Organic Chemistry
Metals and Alloys
Langmuir adsorption model
02 engineering and technology
021001 nanoscience & nanotechnology
Electrochemistry
Surfaces, Coatings and Films
Dielectric spectroscopy
Corrosion
symbols.namesake
Adsorption
Binary acid
0202 electrical engineering, electronic engineering, information engineering
Materials Chemistry
symbols
Erosion corrosion of copper water tubes
0210 nano-technology
Nuclear chemistry
Subjects
Details
- ISSN :
- 2070206X and 20702051
- Volume :
- 55
- Database :
- OpenAIRE
- Journal :
- Protection of Metals and Physical Chemistry of Surfaces
- Accession number :
- edsair.doi...........dc8e3d724edba4899acf24d56033b9da
- Full Text :
- https://doi.org/10.1134/s2070205119060133