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Three-demensional Ni Co NiCo2O4/NF as an efficient electrode for hydrogen evolution reaction

Authors :
Ke Ye
Guiling Wang
Jun Yan
Weizhou Jiao
Kui Cheng
Hongquan Zhang
Kai Zhu
Dongming Zhang
Dianxue Cao
Min Zhu
Xueying Yang
Youzhi Liu
Qing Yan
Source :
International Journal of Hydrogen Energy. 44:226-232
Publication Year :
2019
Publisher :
Elsevier BV, 2019.

Abstract

At present, there is an urgent need for plentiful non-noble metal catalyst to substitute for valuableness platinum based metal catalyst in electrochemical water splitting. Here, we fabricated a three-demensional (3D) Ni Co NiCo2O4 nanosheets electrocatalyst that directly grew on Ni foam firstly and then were reduced in 0.1 mol dm−3 sodium borohydride solution. This electrode exhibited high activity in 1.0 mol dm−3 KOH solution with an onset potential of ∼40 mV and a tafel slope of 77 mV dec−1. Furthermore, the Ni Co NiCo2O4/NF electrode showed a splendid durability during long-playing electrochemical test. Our work may provide an inexpensive, easy-to-obtain and excellent catalyst candidate for future electrolytic water research and industry studies that may involve hydrogen applications in the future.

Details

ISSN :
03603199
Volume :
44
Database :
OpenAIRE
Journal :
International Journal of Hydrogen Energy
Accession number :
edsair.doi...........dc879b0250a35692709b883eee1ac03a
Full Text :
https://doi.org/10.1016/j.ijhydene.2018.03.050