Evidence for the existence of Cu+ and Cu(CN)2 ? in supported copper cyanide reagents

Authors :: Stephen J. Brown
James H. Clark
Catherine V. A. Duke
Jack M. Miller
Source :: Journal of the Chemical Society, Chemical Communications. :877
Publication Year :: 1986
Publisher :: Royal Society of Chemistry (RSC), 1986.
Abstract: I.r. analysis of supported CuCN reagents suggests that the active forms of these materials in nucleophilic cyanations contain the ions Cu+ and Cu(CN)2–; this is the first report of an active solid form of CuCN.

Subjects :: chemistry.chemical_compound
Nucleophile
chemistry
Cyanide
Reagent
Inorganic chemistry
Molecular Medicine
chemistry.chemical_element
Copper
Ion

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