ChemInform Abstract: Catalytic Amide Allylation of α-Ketoesters: Extremely High Enantioselective Synthesis of Ester Functionalized α-Methylene-γ-butyrolactones

Authors :: Masahiro Ishida
Masami Sakamoto
Yusuke Murata
Fumitoshi Yagishita
Tetsuya Sengoku
Hidemi Yoda
Masaki Takahashi
Source :: ChemInform. 46
Publication Year :: 2014
Publisher :: Wiley, 2014.
Abstract: The previously reported carbonyl allylation of isatin derivatives with β-amido-functionalized allylstannanes is extended towards the challenging utilization of α-ketoesters as acyclic 1,2-dicarbonyl substrates.

Subjects :: chemistry.chemical_compound
chemistry
Isatin
Amide
Enantioselective synthesis
General Medicine
Methylene
Medicinal chemistry
Catalysis

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