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Mechanical response and network characterization of conductive polyaniline/polyacrylamide gels
- Source :
- Materials Chemistry and Physics. 187:88-95
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- Electroactive gels based on polyaniline (PANI) and polyacrylamide (PAAm) were prepared by polymerization of aniline in the solution of linear PAAm and subsequent precipitation of PANI/PAAm dispersion in acetone. It has been shown that the composite gels are capable to swelling in water acid and base solutions and dimethyl sulfoxide. It was established by mechanical tests and dynamic oscillatory measurements that the swollen gels demonstrate the elastic response like a covalently crosslinked network but with strong physical interactions between the chains. It is supposed that the observed mechanical elasticity is due to the certain number of elastically effective chemical bonds between PANI and PAAm chains. It is proved that the structure of the samples containing space continuous phase of PANI in the network of PAAm provides them mechanical integrity, good-quality mechanical response, swelling ability and electrical activity.
- Subjects :
- chemistry.chemical_classification
Materials science
Polyacrylamide
Composite number
02 engineering and technology
Polymer
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
01 natural sciences
0104 chemical sciences
chemistry.chemical_compound
Aniline
chemistry
Polymerization
Covalent bond
Polyaniline
medicine
General Materials Science
Composite material
Swelling
medicine.symptom
0210 nano-technology
Subjects
Details
- ISSN :
- 02540584
- Volume :
- 187
- Database :
- OpenAIRE
- Journal :
- Materials Chemistry and Physics
- Accession number :
- edsair.doi...........da2d7864b640ab0c58e9bc4d25a0acb2