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A Modified Recipe and Variations for the Briggs–Rauscher Oscillating Reaction

Authors :
Stanley D. Furrow
Source :
Journal of Chemical Education. 89:1421-1424
Publication Year :
2012
Publisher :
American Chemical Society (ACS), 2012.

Abstract

A modified recipe for the Briggs–Rauscher oscillating reaction is suggested. The modified recipe, [H2SO4] = 0.10 M, [KIO3] = 0.020 M, [NaIO4] = 0.00062 M, [malonic acid] = 0.050 M, [MnSO4] = 0.0067 M, [H2O2] = 1.0 M with 0.01% starch, turns blue almost immediately, then oscillations start with two “slow” (∼25 s) cycles, then settle into regular approximately 12–15 s cycles. Oscillations end with a clear solution, avoiding cleanup of solid iodine resulting from the “standard” recipe, so that only neutralization of excess acid is needed before disposal. Effects of concentration variations are presented.

Details

ISSN :
19381328 and 00219584
Volume :
89
Database :
OpenAIRE
Journal :
Journal of Chemical Education
Accession number :
edsair.doi...........d9f59923a0bbb55c9767562577d86ae2
Full Text :
https://doi.org/10.1021/ed200764r