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Enhanced catalytic activity over MIL-100(Fe) with coordinatively unsaturated Fe2+/Fe3+ sites for selective oxidation of H2S to sulfur
- Source :
- Chemical Engineering Journal. 374:793-801
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- The selective oxidation of H2S, which can eliminate H2S and recover sulfur as a useful resource, is a promising strategy because of its low capital cost and thermodynamically unlimited nature. However, there are obstacles in the development of stable and efficient catalysts to meet the needs of practical cases. Herein, we disclose the use of porous MIL-100(Fe) with coordinatively unsaturated (CUS) Fe2+/Fe3+ sites (denoted as CUS-MIL-100(Fe)) as efficient and stable catalyst for H2S removal. The catalyst is prepared via a simple hydrothermal process using iron powder and 1,3,5-benzenetricarboxylates (H3BTC) as raw materials, and its physicochemical properties have been studied by XPS, BET, ICP-OES, EPR, XRD, and in-situ DRIFTS techniques. The results reveal that the desulfurization performance of the CUS-MIL-100(Fe) catalyst is higher than that of commercial Fe2O3, achieving near 100% H2S conversion and 100% S selectivity at 100–190 °C. Importantly, the H2S conversion and S selectivity over CUS-MIL-100(Fe) are 100% and 95.1% in a continuous run of over 100 h, while those of Fe2O3 are only 42.6% and 19.4% after 13 h. This can be ascribed to the unique characteristics of CUS-MIL-100(Fe), such as the presence of Fe2+/Fe3+ CUSs, large specific surface area, and regular pore structure.
- Subjects :
- Chemistry
General Chemical Engineering
Inorganic chemistry
chemistry.chemical_element
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Sulfur
Industrial and Manufacturing Engineering
Hydrothermal circulation
0104 chemical sciences
Flue-gas desulfurization
Catalysis
Iron powder
X-ray photoelectron spectroscopy
Specific surface area
Environmental Chemistry
0210 nano-technology
Selectivity
Subjects
Details
- ISSN :
- 13858947
- Volume :
- 374
- Database :
- OpenAIRE
- Journal :
- Chemical Engineering Journal
- Accession number :
- edsair.doi...........d9d9f7e30cc2319835fdf4c6992cb352