Synthesis, Structure, Luminescest and Thermal Stable Properties of a Silver(I) Coordination Polymer Constructed from 2,4-Dichlorophenoxyacetic Acid and 1,3-Bis(4-Pyridyl) Propane Ligands

A novel complex of [Ag (poa)(bpp)] n (poa:2,4-Dichlorophenoxyacetic acid;bpp: 1,3-Bis (4-pyridyl) propane) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to Monoclinic system with space group P21/c,a=8.849(4)Å,b=26.654(13)Å,c=9.821(5)Å,α=90°,β=111.257(8)°,γ=90°,V=2158.7(17)Å3,Z=4,Dc=1.619 g/cm3,μ=1.206 mm-1,F(000)=1056. Final indices isR=0.0331,wR=0.0851. Therm al stability and luminescent property of compound have also been nvestigated.