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Ethyl 2-benzyl-2-nitro-3-phenylpropanoate

Authors :
Robert P. Hammer
Tod J. Miller
Frank R. Fronczek
Yanwen Fu
Source :
Acta Crystallographica Section C Crystal Structure Communications. 56:e574-e575
Publication Year :
2000
Publisher :
International Union of Crystallography (IUCr), 2000.

Abstract

The title compound, C18H19NO4, is the key synthetic intermediate in the preparation of α,α-di­benzyl-α-amino acid (di­benzyl­glycine, Dbg), the disubstituted homologue of phenyl­alanine, following the di­alkyl­ation of ethyl nitro­acetate. The mol­ecule does not have its potential mirror symmetry in the crystal, with the two benzyl groups forming N—C—C—C torsion angles of 60.31 (13) and 79.89 (13)°.

Details

ISSN :
01082701
Volume :
56
Database :
OpenAIRE
Journal :
Acta Crystallographica Section C Crystal Structure Communications
Accession number :
edsair.doi...........d82908872afa6e1da2b52c73babd916d