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A fluxional binuclear nickel(I) complex and evidence for reversible A-frame formation
- Source :
- Inorganic Chemistry. 31:904-909
- Publication Year :
- 1992
- Publisher :
- American Chemical Society (ACS), 1992.
-
Abstract
- The synthesis, structure, and fluxionality of the unusual dinickel(I) complex [Ni 2 Cl 2 (μ-CO)(μ-dppm) 2 ] (1a), dppm=Ph 2 PCH 2 PPh 2 are described. Complex 1a is formed by reaction of nickel(0) with nickel(II), in particular by reaction of [Ni 2 (CO) 2 (μ-CO)(μ-dppm) 2 ] with [NiCl 2 (dppm) 2 ] or of [Ni(CO) 2 (dppm-P) 2 ] with NiCl 2 .6H 2 O
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 31
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry
- Accession number :
- edsair.doi...........d6dfef0d26970a56a5190682fa9a2f8c